Nonlinear Optical Properties of Silver Nanoparticles: A Comprehensive Review

Document Type : Review article

Authors

1 Laser-Matter Interaction Laboratory, Department of Physics, COMSATS University Islamabad, Park Road, Islamabad 45550, Pakistan

2 Laser Institute for Research and Applications LIRA, Beni-Suef University, Beni-Suef 62511, Egypt

3 Laser Institute for Research and Applications LIRA, Beni-Suef University, Beni-Suef 62511, Egypt; Department of Engineering, Faculty of Advanced Technology and Multidiscipline, Universitas Airlangga, Indonesia

Abstract

Nonlinear optics has become an essential area of study for understanding and harnessing the complex light-matter interactions that occur in molecules, nanostructures, and advanced materials. This review introduces a summary of the latest advancements, with a particular focus on the nonlinear optical characteristics of noble metal nanoparticles, especially silver nanoparticles (AgNPs). These nanomaterials have gained significant interest due to their typical plasmonic features and size-dependent behavior. Silver nanoparticle colloids demonstrate enhanced light absorption at high intensities, known as reverse saturable absorption, along with a self-defocusing optical response characterized by a negative nonlinear refractive index. It has been observed that the size of noble metal nanoparticles significantly influences their nonlinear optical properties. The thermal lens phenomenon was addressed utilizing a unique approach that considers the cumulative thermal lensing effect induced in the sample caused by high-repetition-rate femtosecond laser pulses. The article highlights current challenges and prospects in the field, particularly in the development of nonlinear optical materials for photonic, sensing, and optical limiting applications.

Keywords

Main Subjects